Gas Pressure

Advertisements
Advertisements

Related Posts:


The left side of this figure includes a graphic of the earth with an inverted rectangular prism extending from a point on it. Near the top of the image, the label, “square inch column of air molecules” is connected to the prism with a line segment. This label is also connected with a line segment to a downward pointing arrow at the right side of the figure. Beneath the arrow is a red circle labeled, “atmospheric pressure.” A narrow rectangle with a dashed line border extends from the bottom of the arrow vertically through the circle. Directly beneath this rectangle at the lower edge of the circle is a hand with a thumb appearing to be resting on a tabletop. The thumb is connected with a line segment to the label, “14.7 lbs of pressure on 1 square inch.” The red circle is sitting on top of the thumb.
Figure 1. The atmosphere above us exerts a large pressure on objects at the surface of the earth, roughly equal to the weight of a bowling ball pressing on an area the size of a human thumbnail. Source: OpenStax Chemistry 2e

Gas Pressure (OpenStax Chemistry 2e)

The earth’s atmosphere exerts a pressure, as does any other gas. Although we do not normally notice atmospheric pressure, we are sensitive to pressure changes—for example, when your ears “pop” during take-off and landing while flying, or when you dive underwater. Gas pressure is caused by the force exerted by gas molecules colliding with the surfaces of objects (Figure 1). Although the force of each collision is very small, any surface of appreciable area experiences a large number of collisions in a short time, which can result in a high pressure. In fact, normal air pressure is strong enough to crush a metal container when not balanced by equal pressure from inside the container.

Atmospheric pressure is caused by the weight of the column of air molecules in the atmosphere above an object, such as the tanker car. At sea level, this pressure is roughly the same as that exerted by a full-grown African elephant standing on a doormat, or a typical bowling ball resting on your thumbnail. These may seem like huge amounts, and they are, but life on earth has evolved under such atmospheric pressure. If you actually perch a bowling ball on your thumbnail, the pressure experienced is twice the usual pressure, and the sensation is unpleasant.

In general, pressure is defined as the force exerted on a given area: P = F/A . Note that pressure is directly proportional to force and inversely proportional to area. Thus, pressure can be increased either by increasing the amount of force or by decreasing the area over which it is applied; pressure can be decreased by decreasing the force or increasing the area.

Let’s apply this concept to determine which would be more likely to fall through thin ice in Figure 2—the elephant or the figure skater? A large African elephant can weigh 7 tons, supported on four feet, each with a diameter of about 1.5 ft (footprint area of 250 in2), so the pressure exerted by each foot is about 14 lb/in2:

The figure skater weighs about 120 lbs, supported on two skate blades, each with an area of about 2 in2, so the pressure exerted by each blade is about 30 lb/in2:

Even though the elephant is more than one hundred-times heavier than the skater, it exerts less than one-half of the pressure and would therefore be less likely to fall though thin ice. On the other hand, if the skater removes her skates and stands with bare feet (or regular footwear) on the ice, the larger area over which her weight is applied greatly reduces the pressure exerted:

This figure includes two photographs. Figure a is a photo of a large gray elephant on grassy, beige terrain. Figure b is a photo of a figure skater with her right skate on the ice, upper torso lowered, arms extended upward behind her chest, and left leg extended upward behind her.
Figure 2. Although (a) an elephant’s weight is large, creating a very large force on the ground, (b) the figure skater exerts a much higher pressure on the ice due to the small surface area of her skates. (credit a: modification of work by Guido da Rozze; credit b: modification of work by Ryosuke Yagi)

The SI unit of pressure is the pascal (Pa), with 1 Pa = 1 N/m2, where N is the newton, a unit of force defined as 1 kg m/s2. One pascal is a small pressure; in many cases, it is more convenient to use units of kilopascal (1 kPa = 1000 Pa) or bar (1 bar = 100,000 Pa). In the United States, pressure is often measured in pounds of force on an area of one square inch—pounds per square inch (psi)—for example, in car tires. Pressure can also be measured using the unit atmosphere (atm), which originally represented the average sea level air pressure at the approximate latitude of Paris (45°). Table 1 provides some information on these and a few other common units for pressure measurements.

PRESSURE UNITS

Unit Name and AbbreviationDefinition or Relation to Other Unit
pascal (Pa)1 Pa = 1 N/m2
recommended IUPAC unit
kilopascal (kPa)1 kPa = 1000 Pa
pounds per square inch (psi)air pressure at sea level is ~14.7 psi
atmosphere (atm)1 atm = 101,325 Pa = 760 torr
air pressure at sea level is ~1 atm
bar (bar, or b)1 bar = 100,000 Pa (exactly)
commonly used in meteorology
millibar (mbar, or mb)1000 mbar = 1 bar
inches of mercury (in. Hg)1 in. Hg = 3386 Pa
used by aviation industry, also some weather reports
torr1 torr=1760atm1 torr=1760atm
named after Evangelista Torricelli, inventor of the barometer
millimeters of mercury (mm Hg)1 mm Hg ~1 torr

We can measure atmospheric pressure, the force exerted by the atmosphere on the earth’s surface, with a barometer (Figure 3). A barometer is a glass tube that is closed at one end, filled with a nonvolatile liquid such as mercury, and then inverted and immersed in a container of that liquid. The atmosphere exerts pressure on the liquid outside the tube, the column of liquid exerts pressure inside the tube, and the pressure at the liquid surface is the same inside and outside the tube. The height of the liquid in the tube is therefore proportional to the pressure exerted by the atmosphere.

This figure shows two barometers. The barometer to the left contains a shallow reservoir, or open container, of mercury. A narrow tube extends upward from the reservoir above the reservoir. This tube is sealed at the top. To the right, a second similar setup is shown with a reservoir filled with water. Line segments connect the label “vacuum” to the tops of the two narrow tubes. The tube on the left shows the mercury in the reservoir extending in a column upward in the narrow tube. Similarly, the tube on the right shows the water in the reservoir extending upward into the related narrow tube. Double-headed arrows extend from the surface of each liquid in the reservoir to the top of the liquid in each tube. A narrow column or bar extends from the surface of the reservoir to the same height. This bar is labeled “atmospheric pressure.” The level of the water in its tube is significantly higher than the level of mercury in its tube.
Figure 3. In a barometer, the height, h, of the column of liquid is used as a measurement of the air pressure. Using very dense liquid mercury (left) permits the construction of reasonably sized barometers, whereas using water (right) would require a barometer more than 30 feet tall. Source: OpenStax Chemistry 2e

If the liquid is water, normal atmospheric pressure will support a column of water over 10 meters high, which is rather inconvenient for making (and reading) a barometer. Because mercury (Hg) is about 13.6-times denser than water, a mercury barometer only needs to be 1/13.6 as tall as a water barometer—a more suitable size. Standard atmospheric pressure of 1 atm at sea level (101,325 Pa) corresponds to a column of mercury that is about 760 mm (29.92 in.) high. The torr was originally intended to be a unit equal to one millimeter of mercury, but it no longer corresponds exactly. The pressure exerted by a fluid due to gravity is known as hydrostatic pressure, p:

where h is the height of the fluid, ρ is the density of the fluid, and g is acceleration due to gravity.

A manometer is a device similar to a barometer that can be used to measure the pressure of a gas trapped in a container. A closed-end manometer is a U-shaped tube with one closed arm, one arm that connects to the gas to be measured, and a nonvolatile liquid (usually mercury) in between. As with a barometer, the distance between the liquid levels in the two arms of the tube (h in the diagram) is proportional to the pressure of the gas in the container. An open-end manometer (Figure 4) is the same as a closed-end manometer, but one of its arms is open to the atmosphere. In this case, the distance between the liquid levels corresponds to the difference in pressure between the gas in the container and the atmosphere.

Three diagrams of manometers are shown. Each manometer consists of a spherical pink container filled with gas on the left that is connected to a U-shaped, sealed tube by a valve on its right. The top of the U aligns with the gas-filled sphere and the U, which extends below, contains mercury. The first manometer has a sealed tube. The sealed end to the upper right in the diagram is labeled “closed end” and “vacuum.” The mercury level is higher in the right side of the tube than in the left. The difference in height is labeled “h.” Beneath this manometer illustration appears the label P subscript gas equal sign h rho g. The second manometer has an open-ended tube, which is labeled “open end.” At this opening in the upper right of the diagram is the label P subscript atm. The mercury level is higher in the left side of the tube than in the right. This difference in height is labeled “h.” Beneath this manometer illustration appears the label P subscript gas equal sign P subscript atm minus sign h rho g. The third manometer has an open-ended tube and is similar to the second manometer except that the mercury level is higher in the right side of the tube than in the left. This difference in height is labeled “h.” Beneath this manometer illustration appears the label P subscript gas equal sign P subscript a t m plus h rho g.
Figure 4. A manometer can be used to measure the pressure of a gas. The (difference in) height between the liquid levels (h) is a measure of the pressure. Mercury is usually used because of its large density. Source: OpenStax Chemistry 2e

Source:

Flowers, P., Theopold, K., Langley, R., & Robinson, W. R. (2019, February 14). Chemistry 2e. Houston, Texas: OpenStax. Access for free at: https://openstax.org/books/chemistry-2e

Advertisements
Advertisements

Related Research

Research Article: Pressure-induced transformation of CH3NH3PbI3: the role of the noble-gas pressure transmitting media

Date Published: June 01, 2019 Publisher: International Union of Crystallography Author(s): Alla Arakcheeva, Volodymyr Svitlyk, Eleonora Polini, Laura Henry, Dmitry Chernyshov, Andrzej Sienkiewicz, Gaétan Giriat, Anastasiia Glushkova, Marton Kollar, Bálint Náfrádi, Laszlo Forro, Endre Horváth. http://doi.org/10.1107/S2052520619004554 Abstract: A structural study of methyl­ammonium lead triiodide [CH3NH3PbI3 (MAPbI3)], at high pressures up to 20 GPa using noble gases … Continue reading

Research Article: Comparison of two portable clinical analyzers to one stationary analyzer for the determination of blood gas partial pressures and blood electrolyte concentrations in horses

Date Published: February 15, 2019 Publisher: Public Library of Science Author(s): Katharina Kirsch, Johann Detilleux, Didier Serteyn, Charlotte Sandersen, Lisa M Katz. http://doi.org/10.1371/journal.pone.0211104 Abstract: Portable blood gas analyzers are used to facilitate diagnosis and treatment of disorders related to disturbances of acid-base and electrolyte balance in the ambulatory care of equine patients. The aim of … Continue reading

Research Article: Combined Effects of Ventilation Mode and Positive End-Expiratory Pressure on Mechanics, Gas Exchange and the Epithelium in Mice with Acute Lung Injury

Date Published: January 9, 2013 Publisher: Public Library of Science Author(s): Apiradee Thammanomai, Hiroshi Hamakawa, Erzsébet Bartolák-Suki, Béla Suki, Derek Abbott. http://doi.org/10.1371/journal.pone.0053934 Abstract: The accepted protocol to ventilate patients with acute lung injury is to use low tidal volume (VT) in combination with recruitment maneuvers or positive end-expiratory pressure (PEEP). However, an important aspect of mechanical … Continue reading

Research Article: Analysis of the coal seam spalling–failure mechanism based on the seepage instability theory

Date Published: July 18, 2019 Publisher: Public Library of Science Author(s): Hengjie Qin, Jianping Wei, Sen Li, Jianguo Wang. http://doi.org/10.1371/journal.pone.0219735 Abstract: Coal and gas outburst is a common coal-rock dynamic disaster. Such accidents frequently occur, and the mechanism underlying the occurrence of these outbursts is complex. As a typical failure mode of a gas-filled and … Continue reading