Research Article: [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro­form disolvate

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Omar bin Shawkataly, Imthyaz Ahmed Khan, Siti Syaida Sirat, Ching Kheng Quah, Hoong-Kun Fun.

http://doi.org/10.1107/S1600536812023227

Abstract

In the title solvated triangulo-triruthenium compound, [Ru3(C18H15O3P)(C29H30P2)(CO)9]·2CHCl3, the bis­(di-o-tolyl­phosphan­yl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru3 triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl­phosphanyl groups of the dtpm ligand. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into chains along [010].

Partial Text

For general background to triangulo-triruthenium compounds with general formula [Ru3(CO)12-nLn] (L = group 15 ligand) see: Bruce et al. (1985 ▶,1988a ▶,b ▶); Shawkataly et al. (1998 ▶, 2004 ▶, 2010 ▶, 2011 ▶). For the preparation of the dtpm ligand, see: Filby et al. (2006 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

 

Source:

http://doi.org/10.1107/S1600536812023227