Research Article: 1-Cyano­methyl-4-aza-1-azoniabicyclo­[2.2.2]octane tetra­fluoro­borate monohydrate

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): Ying Cai.

http://doi.org/10.1107/S1600536810017757

Abstract

In the title compound, C8H14N3+·BF4−·H2O, the cation, anion and water molecule all lie on mirror planes. The BF4− anion is disordered over two orientations with occupancies refined to 0.57 (2) and 0.43 (2). The water mol­ecule is linked to the cation via an O—H⋯N hydrogen bond. Weak inter­molecular O—H⋯F, C—H⋯O and C—H⋯F hydrogen bonds consolidate the crystal packing.

Partial Text

For applications of 1,4-diaza­bicyclo­[2.2.2]octane derivatives, see: Basaviah et al. (2003 ▶); Almarzoqi et al. (1986 ▶). For a related structure, see: Batsanov et al. (2005 ▶).

 

Source:

http://doi.org/10.1107/S1600536810017757

 

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