Research Article: 1-Fluoro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodoxole

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Claude Y. Legault, Julie Prévost.

http://doi.org/10.1107/S1600536812012822

Abstract

The asymmetric unit of the title compound, C9H10FIO, contains two independent mol­ecules which are weakly bound by inter­molecular O⋯I inter­actions [3.046 (4) and 2.947 (4) Å]. The two covalent I—F bonds are slightly longer than the two I—O bonds.

Partial Text

For information on the chemistry of hypervalent compounds, see: Zhdankin & Stang (2002 ▶); Wirth (2005 ▶). For the synthesis and structural analysis of the bromo analog of the title compound, see: Braddock et al. (2006 ▶). For the synthesis and structural analysis of the chloro analog of the title compound, see: Amey & Martin (1979 ▶); Niedermann et al. (2010 ▶). For related information on the trans effect in hypervalent iodine compounds, see: Ochiai et al. (2006 ▶).

 

Source:

http://doi.org/10.1107/S1600536812012822