Research Article: 1-(Phenyl­sulfon­yl)naphthalene

Date Published: August 01, 2012

Publisher: International Union of Crystallography

Author(s): Ying Fu, Wenbo Zhu, Hongxia Hou, Yinxia He, Hulin Li.

http://doi.org/10.1107/S1600536812030929

Abstract

In the title compound, C16H12O2S, the phenyl ring is nearly perpendicular to the naphthalene system [dihedral angle = 80.3 (1)°]. The packing is consolidated by a weak C—H⋯π inter­action involving neighbouring naphthalene and benzene rings. In addition, there exist two different offset π–π stacking inter­actions between benzene rings and between naphthalene systems of symmetry-related mol­ecules [centroid–centroid distances = 3.876 (9) and 3.566 (4) Å, and slippage = 1.412 and 0.554 Å, respectively.

Partial Text

For recent reports on the synthesis of aryl­sulfones, see: Boroujeni (2010 ▶); Bahrami et al. (2008 ▶). For their application, see: Borys et al. (2012 ▶); Padwa et al. (1990 ▶); Block (1992 ▶); Mackinnon & Wang (1998 ▶). For single-crystal structures of sulfones, see: Chawdhury & Hargreaves (1971 ▶); Bacon & Curry (1960 ▶); Sime & Abrahams (1960 ▶); Jeyaraman & Velmurugan (1997 ▶).

 

Source:

http://doi.org/10.1107/S1600536812030929

 

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