Research Article: 1,1′-(Ethane-1,2-di­yl)bis­(1,4,7-triazonane)

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): James C. Knight, Ian A. Fallis.

http://doi.org/10.1107/S1600536810019562

Abstract

In the centrosymmetric title compound (dtne), C14H32N6, two 1,4,7-triaza­cyclo­nonane (tacn, or 1,4,7-triazonane) moieties are linked together each at an amino position by a single ethyl­ene spacer. The mol­ecular packing is supported by pairs of inter­molecular N—H⋯N hydrogen bonds, which form R22(22) ring motifs and link the mol­ecules into infinite chains running parallel to the a axis.

Partial Text

For an investigation into the coordination chemistry of dtne derivatives and similarly bridged polyaza macrocyclic frameworks, see: Schröder et al. (2000 ▶). For dinuclear metal complexes of related ligands, see: Sinnecker et al. (2004 ▶); Marlin et al. (2005 ▶). For the crystal structure of the related compound 1,4,7-triaza­cyclo­nonane (tacn), see: Battle et al. (2005 ▶). For the structures of other metal complexes of dtne, see: Li et al. (2009 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶). For the preparation of a similar compound, see: Burdinski et al. (2000 ▶).

 

Source:

http://doi.org/10.1107/S1600536810019562

 

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