Date Published: July 01, 2011
Publisher: International Union of Crystallography
Author(s): Mohd Faizal Md Nasir, Ibrahim N. Hassan, Bohari Yamin, W. R. W Daud, Mohammad B. Kassim.
In the title compound, C22H19ClN2OS, the thiono and carbonyl groups are trans positioned with respect to a partially double C—N bond. The amide group is twisted relative to the thiourea fragment, forming a dihedral angle of 46.75 (11)°. In the crystal, intermolecular N—H⋯S and C—H⋯O hydrogen bonds link the molecules into a one-dimensional polymeric structure parallel to the c axis.
For related structures and background references, see: Al-abbasi & Kassim (2011 ▶); Nasir et al. (2011 ▶). For metal complexes of benzoylthioureas, see: Weiqun et al. (2005 ▶); Circu et al. (2009 ▶). For the synthetic procedure, see: Hassan et al. (2008 ▶).