Research Article: 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside

Date Published: March 01, 2012

Publisher: International Union of Crystallography

Author(s): Runan Tian, Haoriqinbatu, Hongchang Liu, Xiaoming Wang, Yonghua Yang.

http://doi.org/10.1107/S1600536812004369

Abstract

The title compound, C19H19NO10, was obtained from the reaction of α-d-1-bromo-2,3,4-tri-O-acetylxylose with N-hy­droxy­phthalimide in the presence of potassium carbonate. The asymmetric unit contains two independent mol­ecules, in which the O—CH—O—N torsion angles are 73.0 (4) and 65.0 (4)°. The hexa­pyranosyl rings adopt chair conformations and the substituent groups are in equatorial positions. In the crystal, mol­ecules are linked by nonclassical C—H⋯O hydrogen bonds.

Partial Text

For related structures, see: Yang et al. (2004 ▶); Wang et al. (2008 ▶); Bai et al. (2008 ▶).

 

Source:

http://doi.org/10.1107/S1600536812004369