Research Article: 1d-1-O-tert-Butyl­diphenyl­silyl-2,3,6-O-tris­(meth­oxy­methyl­ene)-myo-inositol 4,5-bis­(dibenzyl­phosphate)

Date Published: March 01, 2012

Publisher: International Union of Crystallography

Author(s): Regan J. Anderson, Graeme J. Gainsford.

http://doi.org/10.1107/S1600536812008069

Abstract

The title compound [systematic name: tetra­benzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyl­diphenyl­sil­yloxy)-3,5,6-tris­(meth­oxy­meth­oxy)cyclo­hexane-1,2-diyl bis­phosphate], C56H68O15P2Si, was isolated as an inter­mediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the crystal, the mol­ecules are connected via one methyl­ene C—H⋯π and two weak phen­yl–ether C—H⋯O inter­actions. One benz­yloxy group is disordered over two overlapping positions with an occupancy ratio of 0.649 (7):0.351 (7).

Partial Text

For background material on the synthesis, see: Kubiak & Bruzik (2003 ▶). For structurally similar compounds, see: Bello et al. (2007 ▶); Sato et al. (2008 ▶). For the Cambridge Structural Database, see: Allen (2002 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶).

 

Source:

http://doi.org/10.1107/S1600536812008069