Research Article: (1E,2E)-1,2-Bis(3-bromo-4-meth­oxy­benzyl­idene)hydrazine

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Jerry P. Jasinski, James A. Golen, C. S. Chidan Kumar, B. Narayana, H. S. Yathirajan.

http://doi.org/10.1107/S1600536811016904

Abstract

In the title compound, C16H14Br2N2O2, the dihedral angle between the mean planes of the two benzene rings is 33.4 (2)°. The hydrazine group is twisted slightly, with C—N—N—C and C—C—N—N torsion angles of 167.5 (4) and 177.2 (4)/174.2 (4)°, respectively.

Partial Text

For anti­tubercular behaviour in isonicotinoyl hydrazones, see: Kucukguzel et al. (1999 ▶); Rollas et al. (2002 ▶). For the coordination chemistry of azine compounds containing both a diamine linkage and an N—N bond, see: Armstrong et al. (1998 ▶); Kesslen & Euler (1999 ▶); Kundu et al. (2005 ▶); Xu et al. (1997 ▶). For related structures, see: Zheng et al. (2005 ▶, 2006 ▶); Zheng & Zhao (2006 ▶); Odabaşoğlu et al. (2007 ▶).

 

Source:

http://doi.org/10.1107/S1600536811016904

 

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