Date Published: May 01, 2012
Publisher: International Union of Crystallography
Author(s): Ryszard Lazny, Karol Wolosewicz, Zbigniew Dauter, Krzysztof Brzezinski.
In the crystal structure of the racemic title compound, C22H25NO2, solved and refined against sychrotron diffraction data, the hydroxy group and the carbonyl O atom participate in the formation of O—H⋯O hydrogen bonds between pairs of enantiomers related by a crystallographic centre of symmetry.
For recent background literature on the synthesis, structure and applications of related granatane-derived aldols, see: Lazny et al. (2011a ▶) and references cited therein. For the stereoselective syntheses, applications and structures of related tropinone aldols, see: Sienkiewicz et al. (2009 ▶); Lazny et al. (2011b ▶); Brzezinski et al. (2012 ▶) and for related nortropinone aldols, see: Lazny et al. (2001 ▶, 2010 ▶); Lazny & Nodzewska (2003 ▶).