Research Article: {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Xin-Zhi Sun.


In the title dioxidovanadium complex, [V(C13H17N2O)O2], the VV atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, mol­ecules are connected by N—H⋯O and N—H⋯(O,O) hydrogen bonds, forming a tetra­mer.

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For related structures and their proporties, see: Agarwal & Prasad (2006 ▶); Chohan & Sumrra (2010 ▶); Huo et al. (2004 ▶); Jing et al. (2005 ▶); Lodyga-Chruscinska et al. (2008 ▶); Xie et al. (2004 ▶); Yuan et al. (2009 ▶).