Research Article: 2-[3-(1,3-Benzothia­zol-2-yl)-2,2-di­methyl­prop­yl]-2-methyl-2,3-di­hydro-1,3-benzothia­zole

Date Published: August 01, 2012

Publisher: International Union of Crystallography

Author(s): Sammer Yousuf, Hina Siddiqui, Rabia Farooq, M. Iqbal Choudhary.

http://doi.org/10.1107/S1600536812029297

Abstract

In the title compound, C20H22N2S2, the five-membered thia­zole ring of the 2-methyl-2,3-dihydro-1,3-benzothia­zole unit has an envelope conformation. The dihedral angle between the planar [maximum deviation of 0.014 (1) Å for the S atom] benzothia­zole ring system and the benzene ring is 78.37 (12)°. Two intra­molecular C—H⋯S hydrogen bonds are observed, forming rings of graph-set motif S(6). In the crystal, the molecules are consolidated in pairs through N—H⋯N hydrogen bonds and are arranged parallel to the b axis.

Partial Text

For the biological activity of benzothia­zoles, see: Prabhu et al. (2011 ▶); Chaudhary et al. (2010 ▶): Kaur et al. (2010 ▶). For the crystal structures of closely related compounds see: Ghalib et al. (2011 ▶); Chen et al. (2009 ▶); Brandenburg et al. (1987 ▶).

Source:

http://doi.org/10.1107/S1600536812029297