Research Article: 2-(4-Fluoro­phen­yl)-3-methyl-1H-indole

Date Published: July 01, 2011

Publisher: International Union of Crystallography

Author(s): David B. Cordes, Guoxiong Hua, Alexandra M. Z. Slawin, J. Derek Woollins.


The indole N—H hydrogen in the title compound, C15H12FN, does not display classical hydrogen bonding. Rather it forms an interaction with the π system of an adjacent indole, resulting in weakly inter­acting chains along the [001] direction.

Partial Text

The title compound has previously been prepared by Buu-Hoi & Jacquignon (1949 ▶) and by Kraus & Guo (2009 ▶). For the synthesis of the starting material, 4-fluoro-N-(2-oxo-2-phenyl­eth­yl)benzamide, see: Moriya et al. (1986 ▶). There are no structures of closely related compounds in the literature. For some similar compounds, see: Schmelter et al. (1973 ▶); Konno et al. (2004 ▶); Kumar & Liu (2006 ▶).




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