Date Published: February 01, 2012
Publisher: International Union of Crystallography
Author(s): Jamshid Ashurov, Bakhtiyar Ibragimov, Samat Talipov.
In the crystal structure of the title compound, C6H7N·CH4N2O, the 2-methylpyridine and urea molecules are linked via N—H⋯O and N—H⋯N hydrogen bonds, forming ribbons extending along the a axis. The dihedral angle between the 2-methylpyridine and urea mean planes is 89.09 (9)°. The methyl group shows rotational disorder wherein the H atoms are located over two sets of sites with equal occupancies.
For crystal structures of urea inclusion compounds, see: Izotova et al. (2008 ▶); Chadwick et al. (2009 ▶).