Research Article: (2-Oxo-2H-benzo[h]chromen-4-yl)methyl morpholine-4-carbodithio­ate

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Rajni Kant, Vivek K. Gupta, Kamini Kapoor, Gurvinder Kour, K. Mahesh Kumar, N. M. Mahabaleshwaraiah, O. Kotresh.

http://doi.org/10.1107/S160053681201094X

Abstract

In the title compound, C19H17NO3S2, the morpholine ring is in a chair conformation. In the coumarin ring system, the dihedral angle between the benzene and pyran rings is 3.9 (1)°. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into corrugated layers parallel to (102). The crystal packing also exhibits π–π inter­actions, with distances of 3.644 (1) and 3.677 (1) Å between the centroids of the benzene rings of neighbouring mol­ecules.

Partial Text

For the biological activity of coumarins, see: Kontogiorgis & Hadjipavlou-Litina (2004 ▶). For a related structure, see: Kumar et al. (2012 ▶). For standard bond lengths, see: Allen et al. (1987 ▶).

 

Source:

http://doi.org/10.1107/S160053681201094X