Research Article: 2,17-Dichloro-8,9,10,11-tetra­hydro-19H-dibenzo[k,n][1,10,4,7]dioxadiaza­cyclo­penta­decine-7,12(6H,13H)-dione

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Michaela Pojarová, Michal Dušek, Zdeňka Sedláková, Emanuel Makrlík.

http://doi.org/10.1107/S1600536812020351

Abstract

In the crystal structure of the title compound, C19H18Cl2N2O4, N—H⋯O hydrogen bonds link the mol­ecules into infinite chains along the b axis. The structure also features weak C—H⋯O and C—H⋯Cl hydrogen bonds and C—H⋯π and (lone pair)⋯π inter­actions [Cl⋯centroid = 3.5871 (7) Å]. An intra­molecular N—H⋯O bond occurs.

Partial Text

For the synthesis, see: Ertul et al. (2009 ▶). For applications of macrocycles, see: Hayvali & Hayvali (2005 ▶); Kleinpeter et al. (1997 ▶); Jaiyu et al. (2007 ▶); Christensen et al. (1997 ▶); Alexander (1995 ▶).

Source:

http://doi.org/10.1107/S1600536812020351