Research Article: (2,2′-Bipyridine-κ2N,N′)dichloridobis(4-fluoro­benz­yl)tin(IV)

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Thy Chun Keng, Kong Mun Lo, Seik Weng Ng.

http://doi.org/10.1107/S1600536811015686

Abstract

The six-coordinate SnIV atom in the title compound, [Sn(C7H6F)2Cl2(C10H8N2)], shows a trans-C2SnN2Cl2 octa­hedral coordination [C—Sn—C = 174.81 (10) and 176.71 (9)° in the two independent mol­ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

Partial Text

For the direct synthesis of the organotin chloride reactant, see: Sisido et al. (1961 ▶). For the dibenzyl­dichloridotin–2,2′-bipyridine adduct, see: Tiekink et al. (2000 ▶).

 

Source:

http://doi.org/10.1107/S1600536811015686

 

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