Research Article: (2E)-3-[3-(Benz­yloxy)phen­yl]-1-(2-hy­droxy­phen­yl)prop-2-en-1-one

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Hoong-Kun Fun, Wan-Sin Loh, B. K. Sarojini, V. Musthafa Khaleel, B. Narayana.

http://doi.org/10.1107/S160053681101614X

Abstract

In the title compound, C22H18O3, an intra­molecular O—H⋯O hydrogen bond stabilizes the mol­ecular structure, forming an S(6) ring motif. The central benzene ring forms a dihedral angle of 64.74 (5)° with the phenyl ring and a dihedral angle of 5.58 (5)° with the terminal benzene ring. In the crystal, mol­ecules are linked into columns along the a axis via inter­molecular C—H⋯O hydrogen bonds. C—H⋯π inter­actions involving the centroid of the hy­droxy-substituted benzene ring further stabilize the crystal structure.

Partial Text

For the background to chalcones, see: Awad et al. (1960 ▶); Coudert et al. (1988 ▶); Insuasty et al. (1992 ▶, 1997 ▶); Kolos et al. (1996 ▶); Samshuddin et al. (2010 ▶); Fun et al. (2010 ▶); Sarojini et al. (2006 ▶); Shettigar et al. (2010 ▶); Sharma et al. (1997 ▶); Ravishankar et al. (2003 ▶, 2005 ▶); Butcher et al. (2006 ▶); Narayana et al. (2007 ▶); Sarojini et al. (2007a ▶,b ▶); Jasinski et al. (2011 ▶). For bond-length data, see: Allen et al. (1987 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

 

Source:

http://doi.org/10.1107/S160053681101614X

 

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