Research Article: (2R,4R)-2-Hydr­oxy-4-(2-methoxy­phen­yl)bicyclo­[3.3.1]nonan-9-one

Date Published: August 01, 2009

Publisher: International Union of Crystallography

Author(s): Shuping Luo, Guangcun Zhang, Shuai Zhang, Yifeng Wang, Wei Zhang.

http://doi.org/10.1107/S1600536809028980

Abstract

The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by inter­molecular O—H⋯O hydrogen bonds. The absolute configuration was established by the stereo-selectivity of the asymmetric organocatalysis.

Partial Text

A similar structure is described by Cao et al. (2007 ▶). For general background to organocatalysis, see: List et al. (2000 ▶, 2001 ▶); Notz et al. (2001 ▶).

 

Source:

http://doi.org/10.1107/S1600536809028980

 

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