Date Published: August 01, 2012
Publisher: International Union of Crystallography
Author(s): Samina Khan Yusufzai, Hasnah Osman, Aisyah Saad Abdul Rahim, Suhana Arshad, Ibrahim Abdul Razak.
In the title compound, C13H10N2O2S, the essentially planar 2H-chromene ring system [maximum deviation = 0.0297 (13) Å] and the thiazole ring [maximum deviation = 0.0062 (11) Å] form a dihedral angle of 3.47 (5)°. In the crystal, N—H⋯N and C—H⋯O hydrogen bonds link the molecules into two-dimensional networks parallel to the bc plane. C—H⋯π and π–π [centroid–centroid separation = 3.6796 (8) Å] interactions further stabilize the crystal structure.
For the biological activities of coumarin derivatives, see: Soine (1964 ▶); Wattenberg et al. (1979 ▶); Jung et al. (1999 ▶); Rao et al. (1981 ▶). For a related structure, see: Arshad et al. (2010 ▶, 2011 ▶); Asad et al. (2011 ▶); Yusufzai, Osman, Sulaiman et al. (2012 ▶); Yusufzai, Osman, Abdul Rahim et al. (2012 ▶). For the stability of the temperature controller used for data collection, see: Cosier & Glazer (1986 ▶).