Research Article: 3-(4-Bromo­phenyl­sulfin­yl)-5-chloro-2-methyl-1-benzofuran

Date Published: July 01, 2012

Publisher: International Union of Crystallography

Author(s): Hong Dae Choi, Pil Ja Seo, Uk Lee.

http://doi.org/10.1107/S1600536812025846

Abstract

In the title compound, C15H10BrClO2S, the 4-bromo­phenyl ring makes a dihedral angle of 86.85 (6)° with the mean plane [mean deviation = 0.009 (2) Å] of the benzofuran fragment. In the crystal, mol­ecules are linked by slipped π–π inter­actions between the benzene and the furan rings of adjacent mol­ecules [centroid–centroid distance = 3.884 (2), inter­planar distance = 3.369 (2) and slippage = 1.945 (2) Å], and between the 4-bromo­phenyl rings of adjacent mol­ecules [centroid–centroid distance = 3.882 (2), inter­planar distance = 3.552 (2) and slippage = 1.566 (2) Å]. A Br⋯Br [3.6446 (4) Å] halogen inter­action is also observed.

Partial Text

For background information and the crystal structures of related compounds, see: Choi et al. (2008 ▶, 2010 ▶).

 

Source:

http://doi.org/10.1107/S1600536812025846

 

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