Date Published: August 01, 2012
Publisher: International Union of Crystallography
Author(s): Sharatha Kumar, Sabine Foro, B. Thimme Gowda.
In the title compound, C11H14N2OS, the two N—H bonds are anti to each other and one of them is anti to the C=S and the other is syn. Further, the amide C=S and the C=O groups are anti to each other. The dihedral angle between the benzene ring and the side chain is 83.74 (5)°. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, molecules are linked into inversion dimers by pairs of N—H⋯S interactions.
For studies on the effects of substituents on the structures and other aspects of N-(aryl)-amides, see: Gowda et al. (2006 ▶); Shahwar et al. (2012 ▶), of N-(aryl)-methanesulfonamides, see: Gowda et al. (2007 ▶) and of N-chloroarylsulfonamides, see: Gowda et al. (2005 ▶); Shetty & Gowda (2004 ▶).