Research Article: 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium perchlorate

Date Published: May 01, 2010

Publisher: International Union of Crystallography

Author(s): Tara Shahani, Hoong-Kun Fun, S. Sarveswari, V. Vijayakumar, B. Palakshi Reddy.

http://doi.org/10.1107/S1600536810012900

Abstract

In the title mol­ecular salt, C18H15ClNO+·ClO4−, the quinolin­ium ring system is approximately planar, with a maximum deviation of 0.027 (1) Å. The dihedral angle formed between the mean planes of the quinolinium ring system and the benzene ring is 78.46 (3)°. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. The crystal structure is further consolidated by C—H⋯π inter­actions.

Partial Text

For natural products containing quinolines, see: Michael (1997 ▶); Morimoto et al. (1991 ▶). For the biological activities of quinolines, see: Campbell et al. (1988 ▶); Markees et al. (1970 ▶). For the physiological activities of quinolines, see: Katritzky & Arend (1998 ▶); Jiang & Si (2002 ▶). For related structures, see: Shahani et al. (2010 ▶); Fun et al. (2009 ▶); Loh et al. (2010 ▶). For bond-length data, see: Allen et al. (1987 ▶). For the stability of the temperature controller used for the data collection, see: Cosier & Glazer (1986 ▶).

 

Source:

http://doi.org/10.1107/S1600536810012900

 

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