Research Article: 3-(Adamantan-1-yl)-1-[(4-benzyl­piperazin-1-yl)meth­yl]-4-phenyl-1H-1,2,4-triazole-5(4H)-thione

Date Published: February 01, 2012

Publisher: International Union of Crystallography

Author(s): Ebtehal S. Al-Abdullah, Hanadi H. Asiri, Ali El-Emam, Seik Weng Ng.

http://doi.org/10.1107/S160053681105570X

Abstract

The title mol­ecule, C30H37N5S, displays a chair-shaped piperazine ring, as well as an approximately planar triazole ring [maximum deviation = 0.002 (2) Å] whose phenyl substituent is nearly perpendicular to the mean plane of the five-membered ring [dihedral angle = 80.4 (1)°]. The substit­uents on the piperazine ring occupy equatorial sites. Weak inter­molecular C—H⋯S hydrogen bonding is present in the crystal structure.

Partial Text

For background to 3-(1-adamant­yl)-4-substituted-5-mercapto-1,2,4-triazole derivatives, see: El-Emam & Ibrahim (1991 ▶).

 

Source:

http://doi.org/10.1107/S160053681105570X