Date Published: August 01, 2012
Publisher: International Union of Crystallography
Author(s): Ali A. El-Emam, Ebtehal S. Al-Abdullah, Hanaa M. Al-Tuwaijri, Mohammed Said-Abdelbaky, Santiago García-Granda.
The title compound, C25H35N5S, has an approximately C-shaped conformation. The dihedral angle between the triazole and phenyl planes is 79.5 (2)°. The crystal structure consists of infinite chains parallel to the b axis, constructed by C—H⋯S hydrogen bonds between translation-related molecules. Adjacent chains are linked via weak C—H⋯C interactions between the adamantyl and phenyl groups.
For the biological activity of adamantane derivatives and adamantyl-1,2,4-triazoles, see: Vernier et al. (1969 ▶); Al-Deeb et al. (2006 ▶); Al-Omar et al. (2010 ▶); El-Emam & Ibrahim (1991 ▶); El-Emam et al. (2004 ▶); Kadi et al. (2007 ▶, 2010 ▶). For related adamantyl-1,2,4-triazole structures, see: Al-Tamimi et al. (2010 ▶); Al-Abdullah et al. (2012 ▶); El-Emam et al. (2012 ▶); Lahsasni et al. (2012 ▶).