Date Published: June 01, 2011
Publisher: International Union of Crystallography
Author(s): Xiu-Mei Song, Ning Wang, Zhao-Yang Wang, Zong-Cai Feng.
The title compound, C16H26ClNO3 contains one almost planar furanone ring [maximum deviation of 0.021 (2) Å for the O atom] with a stereogenic center (S) and one cyclohexane ring which displays a chair conformation and has three stereogenic centers [S at the C atom bearing the isopropyl group, R at the C atom attached to the O atom and R at the C atom bearing the methyl group].
For natural products containing a 2(5H)-furanone subunit, see: Ming et al. (2002 ▶). For biologically active 2(5H)-furanones, see: Bailly et al. (2008 ▶). For the synthesis of 2(5H)-furanones with substituents in positions 3 and 4, see: Van Oeveren et al. (1994 ▶); For related structures, see: Chen et al. (1995 ▶); Martín & Mateo (1995 ▶); Gawronski et al. (1997 ▶). For the use of benzimidazoles in organic synthesis, see: Mao et al. (2010 ▶). For standard bond lengths, see: Allen et al. (1987 ▶); Orpen et al. (1989 ▶). For the structures of heterosubstituted 2(5H)-furanones, see: Gawronski et al. (1997 ▶). For the synthesis and structure of optically pure 5-(l-menthyloxy)-3,4-dichloro-2(5H)-furanone, see: Chen & Geng (1993 ▶). For a description of the Cambridge Structural Database, see: Allen (2002 ▶).