Date Published: April 01, 2012
Publisher: International Union of Crystallography
Author(s): Bi-Zeng Mao, Chao Huang, Yu-Zhe Chen, Zhen-Er Lv, Shao-Yuan Chen.
The asymmetric unit in the crystal of the title compound, C15H22O3, contains two independent molecules with similar structures. Each molecule contains two six-membered rings and one five-membered ring. The five-membered ring displays an envelope conformation with the C atom linking the epoxy group as the flap, while the two six-membered rings show half-chair conformations. The two independent molecules are linked by an O—H⋯O hydrogen bond. These dimers are further linked by O—H⋯O hydrogen bonds, forming supramolecular chains running along the a axis.
For the applications of trichodermin derivatives, see: Wei et al. (1974 ▶); Zhang et al. (2007 ▶). For ring conformations, see: Cremer & Pople (1975 ▶). For a related structure, see: Chen et al. (2008 ▶).