Research Article: 4′-tert-Butyl-5-chloro-3H-spiro­[1,3-benzothia­zole-2,1′-cyclo­hexa­ne]

Date Published: May 01, 2012

Publisher: International Union of Crystallography

Author(s): Mehmet Akkurt, Gökçe Cihan-Üstündağ, Gültaze Çapan, Yılmaz Dağdemir, Muhammad Nawaz Tahir.

http://doi.org/10.1107/S1600536812017539

Abstract

In the title compound, C16H22ClNS, the nine-membered 2,3-dihydro-1,3-benzothia­zole ring system is essentially planar, with a maximum deviation of 0.025 (2) Å for the N atom. Its plane is almost perpendicular to the main plane of the substituted cyclo­hexane ring, which adopts a chair conformation. In the crystal, the molecules are linked by C—H⋯π inter­actions.

Partial Text

For the pharmacological activity of benzothia­zole derivatives, see: Coudert et al. (1988 ▶); Karalı et al. (2010 ▶); Palmer et al. (1971 ▶). For the crystal structures of similar compounds, see, for example: Akkurt et al. (2010 ▶); Aryai et al. (1976 ▶); Karalı et al. (2010 ▶). For standard values of bond lengths, see: Allen et al. (1987 ▶). For details of ring-puckering analysis, see: Cremer & Pople (1975 ▶).

 

Source:

http://doi.org/10.1107/S1600536812017539