Research Article: [4-(Dimethyl­amino)­pyridine-κN1]tri­methyl(thio­cyanato-κN)tin(IV)

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Ezzatollah Najafi, Mostafa M. Amini, Seik Weng Ng.

http://doi.org/10.1107/S1600536812022064

Abstract

In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH3)3(NCS)(C7H10N2)], the SnIV atom shows a trans-C3SnN2 trigonal bipyramidal coordination. The SnIV atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

Partial Text

For trimethyl­tin isothio­cyanate, see: Forder & Sheldrick (1970 ▶).

 

Source:

http://doi.org/10.1107/S1600536812022064

 

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