Research Article: 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione

Date Published: May 01, 2009

Publisher: International Union of Crystallography

Author(s): Hoong-Kun Fun, Samuel Robinson Jebas, K. V Sujith, Balakrishna Kalluraya.


In the title compound, C22H26N4OS, the benzene rings of the (2-methyl­prop­yl)phenyl and 4-methoxy­phenyl units form dihedral angles of 66.85 (3) and 25.96 (3)°, respectively, with the triazole ring. The dihedral angle between the two benzene rings is 87.42 (2)°. The –CH(CH3) linkage is disordered over two orientations with occupancies of 0.907 (3) and 0.093 (3). An intra­molecular C—H⋯S hydrogen bond generates an S(6) ring motif. Inter­molecular N—H⋯S hydrogen bonds and C—H⋯π inter­actions are observed.

Partial Text

For the pharmaceutical applications of triazole compounds, see: Amir & Kumar (2007 ▶); Clemons et al. (2004 ▶); Demirbas & Ugurluoglu (2004 ▶); Demirbas et al. (2002 ▶); Johnston (2002 ▶); Shujuan et al. (2004 ▶). For bond-length data, see: Allen et al. (1987 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶). For the stability of the temperature controller used for the data collection, see: Cosier & Glazer (1986 ▶).




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