Research Article: 4-Meth­oxy-N-(4-nitro­benz­yl)aniline

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Kamini Kapoor, Vivek K. Gupta, Indresh Kumar, Nisar A. Mir, Rajni Kant.

http://doi.org/10.1107/S160053681200846X

Abstract

In the title compound, C14H14N2O3, the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the amino­methyl­ene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions are also observed.

Partial Text

For related structures, see: Iwasaki et al. (1988 ▶). For the biological properties of aldimines, see: Rjosk & Neumann (1971 ▶); Hillesheim et al. (1995 ▶). For bond-length data, see: Allen et al. (1987 ▶).

 

Source:

http://doi.org/10.1107/S160053681200846X