Research Article: 4-Methyl­anilinium 2-carb­oxy­acetate

Date Published: July 01, 2012

Publisher: International Union of Crystallography

Author(s): Ying-Chun Wang.

http://doi.org/10.1107/S1600536812024403

Abstract

During the formation of the title salt, C7H10N+·C3H3O4−, an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007 (4) Å]. The mean planes of the carboxyl­ate and carboxyl groups of the anion form a dihedral of 69.67 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the anions and cations, forming a two-dimensional network parallel to the bc plane.

Partial Text

For the structures and properties of related compounds, see: Chen et al. (2001 ▶); Wang et al. (2002 ▶); Xue et al. (2002 ▶); Huang et al. (1999 ▶); Zhang et al. (2001 ▶); Ye et al. (2008 ▶).

 

Source:

http://doi.org/10.1107/S1600536812024403

 

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