Research Article: 4-Nitro-2-phenoxy­aniline

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): H. R. Manjunath, M. T. Shreenivasa, M. Mahendra, T. M. Mohan Kumar, B. E. Kumara Swamy, M. A. Sridhar.

http://doi.org/10.1107/S1600536810012237

Abstract

In the title compound, C12H10N2O3, the oxygen atom bridging the two aromatic rings is in a synperiplanar (+sp) conformation. The dihedral angle between the aromatic rings is 71.40 (12)°. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds.

Partial Text

For the pharmacological properties of nitro-2-phenoxy­aniline, see: Moore & Harrington (1974 ▶); Prasad et al. (2005 ▶). For the herbicidal applications of biphenyl ether derivatives, see: Yu et al., (2008 ▶). For the applications of Schiff bases derived from aromatic amines, see: Singh et al. (1975 ▶); Cimerman et al. (2000 ▶). For their biological and pharmacological acitvity, see: Singh et al. (1975 ▶); Cimerman et al. (2000 ▶); Shah et al. (1992 ▶); Pandeya et al. (1999 ▶); More et al. (2001 ▶). For the preparation of 4-nitro-2-phenoxy­aniline, see: Shreenivasa et al. (2009 ▶). For a related structure, see: Naveen et al. (2006 ▶).

Source:

http://doi.org/10.1107/S1600536810012237