Research Article: 4-Nitro-2-{[(tricyclo­[3.3.1.13,7]decan-1-yl)iminium­yl]meth­yl}phenolate

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Kwang Ha.

http://doi.org/10.1107/S1600536812012597

Abstract

The title compound, C17H20N2O3, is a Schiff base, which is found as a zwitterion in the solid state. The geometry around the iminium N atom indicates sp2-hybridization. The zwitterion shows a strong intra­molecular N—H⋯O hydrogen-bond inter­action between the iminium N atom and the phenolate O atom.

Partial Text

For the crystal structure of 2-[(tricyclo­[3.3.1.13,7]decan-1-yl­imino)­meth­yl]phenol, see: Fernández-G et al. (2001 ▶).

 

Source:

http://doi.org/10.1107/S1600536812012597