Date Published: April 01, 2011
Publisher: International Union of Crystallography
Author(s): Saeed Rayati, Akbar Ghaemi, Behrouz Notash.
In the title compound, [Ni(C19H18Br2N2O2)], the NiII ion, lying on a twofold rotation axis, is coordinated by two N atoms and two O atoms from the Schiff base ligand in a distorted square-planar geometry. Weak intermolecular C—H⋯O hydrogen bonds stabilize the crystal structure.
For the catalytic properties of Schiff base complexes, see: Cozzi (2004 ▶). For related structures see: Fun et al. (2008 ▶); Kargar et al. (2008 ▶). For the synthesis of the ligand, see: Fairhurst et al. (1995 ▶).