Date Published: July 01, 2012
Publisher: International Union of Crystallography
Author(s): Manman Zhang, Li Li, Fugen Yuan, Hui Qian.
The title compound, C34H54N2O2·0.25H2O, the organic molecule, a potential tetradentate ligand with a bulky phenolic donor, has overall mirror symmetry. A partially occupied water molecule of solvation is present in the lattice. The six-membered 1,3-diazinane ring displays a chair conformation. An intramolecular O—H⋯N hydrogen bond ocurs. In the crystal, molecules are linked by O—H⋯O interactions.
For aminobisphenolato ligands in coordination chemistry, see: Wichmann et al. (2012 ▶). For applications of their metal complexes, see: Barroso et al. (2010 ▶); Wong et al. (2010 ▶); Kannan et al. (2008 ▶); Pang et al. (2008 ▶); Tshuva et al. (2001 ▶). For background to the synthetic procedure and related structures, see: Hancock et al. (2011 ▶); Manna et al. (2008 ▶); Mohanty et al. (2008 ▶); Guo et al. (2003 ▶).