Research Article: {4,4′,6,6′-Tetra­bromo-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}copper(II)

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Hadi Kargar, Reza Kia, Mahbubeh Haghshenas, Muhammad Nawaz Tahir.

http://doi.org/10.1107/S1600536812009397

Abstract

In the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an inter­molecular π–π inter­action [centroid–centroid distance = 3.8891 (18) Å].

Partial Text

For standard bond lengths, see: Allen et al. (1987 ▶). For applications of Schiff base ligands in coordination chemistry, see: Granovski et al. (1993 ▶); Blower (1998 ▶). For a related structure, see: Kargar et al. (2008 ▶).

 

Source:

http://doi.org/10.1107/S1600536812009397