Date Published: May 01, 2009
Publisher: International Union of Crystallography
Author(s): Jian-Ning Guan, Rong Wan, Yao Wang, Feng Han, Cheng-Zhen Xu.
The title compound, C9H9N3S, was synthesized by the reaction of 4-methyl-benzoic acid and thiosemicarbazide. The thiadiazol ring adopts a planar conformation and makes a dihedral angle of 31.19 (18)° with the phenyl ring. In the crystal, molecules are linked by N—H⋯N hydrogen bonds.
For applications of thiadiazole ligands, see: Nakagawa et al. (1996 ▶); Wang et al. (1999 ▶); Han et al. (2007 ▶). For bond-length data, see: Allen et al. (1987 ▶).