Research Article: 9-Benzyl-9H-carbazole

Date Published: May 01, 2010

Publisher: International Union of Crystallography

Author(s): Nesimi Uludağ, Murat Ateş, Barış Tercan, Emel Ermiş, Tuncer Hökelek.

http://doi.org/10.1107/S1600536810012444

Abstract

The asymmetric unit of the title compound, C19H15N, contains two crystallographically independent mol­ecules. In both mol­ecules, the planar carbazole moieties [maximum deviations = 0.037 (4) and 0.042 (3) Å] are oriented with respect to the adjacent benzene rings, at dihedral angles of 85.29 (8) and 89.89 (7)°, respectively. In the crystal structure, weak C—H⋯π inter­actions are observed involving the carbazole rings.

Partial Text

For tetra­hydro­carbazole systems present in the framework of a number of indole-type alkaloids of biological inter­est, see: Phillipson & Zenk (1980 ▶); Saxton (1983 ▶); Abraham (1975 ▶). For related structures, see: Hökelek et al. (1994 ▶, 1998 ▶, 1999 ▶, 2004 ▶, 2006 ▶); Patır et al. (1997 ▶); Hökelek & Patır (1999 ▶, 2002 ▶); Çaylak et al. (2007 ▶). For bond-length data, see: Allen et al. (1987 ▶).

 

Source:

http://doi.org/10.1107/S1600536810012444

 

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