Research Article: A new MoVI Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)

Date Published: July 01, 2011

Publisher: International Union of Crystallography

Author(s): Iran Sheikhshoaie, Vratislav Langer, Seyed Ali Yasrebi.

http://doi.org/10.1107/S1600536811020101

Abstract

In the title benzil­idene Schiff base molybdenum(VI) complex, [Mo(C15H12N2O3)O2(CH3OH)], the MoVI ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N′-(3-meth­oxy-2-oxidobenzyl­idene)benzo­hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa­hedral configuration of the MoVI atom. Strong O—H⋯N hydrogen bonds form a C(5) chain around a 21 screw axis. Weak C—H—O hydrogen bonds are also present.

Partial Text

For general background, see: Alizadeh et al. (1999 ▶); Ambroziak et al. (2004 ▶); Archer & Wang (1990 ▶); Bagherzadeh & Amini (2009 ▶); Bagherzadeh et al. (2008 ▶); Bhatia et al. (1981 ▶); Bindlish et al. (1978 ▶); Blake et al. (1995 ▶); Chang et al. (1998 ▶); Costamagna et al. (1992 ▶); Dhar & Taploo (1982 ▶); Hatefi et al. (2009 ▶); Holm (1990 ▶); Jalali-Heravi et al. (1999 ▶); Johnson et al. (1996 ▶); Maurya et al. (1997 ▶); Sheikhshoaie & Fabian (2009 ▶); Yamada (1999 ▶). For details of the synthesis, see: Perrin et al. (1990 ▶). For related structures, see: Dinda et al. (2006 ▶); Glowiak et al. (2003 ▶); Liimatainen et al. (2000 ▶); Monadi et al. (2009 ▶); Niaz et al. (2010 ▶); Pramaniky et al. (2007 ▶); Rao et al. (1999 ▶); Rezaeifard et al. (2010 ▶); Saeednia et al. (2009 ▶); Sheikhshoaie et al. (2009 ▶); Vrdoljak et al. (2010 ▶).

 

Source:

http://doi.org/10.1107/S1600536811020101

 

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