Research Article: Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ3N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)

Date Published: July 01, 2011

Publisher: International Union of Crystallography

Author(s): Nura Suleiman Gwaram, Hamid Khaledi, Hapipah Mohd Ali.

http://doi.org/10.1107/S1600536811022124

Abstract

In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N′,N”-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octa­hedral geometry around the metal atom is completed by two cis-positioned N-bound thio­cyanate ligands and one water mol­ecule. In the crystal, adjacent mol­ecules are linked through O—H⋯O, O—H⋯S and C—H⋯S hydrogen bonds into a three-dimensional supra-mol­ecular structure. An intra­molecular C—H⋯O hydrogen bond also occurs.

Partial Text

For the isostructural Co(II) complex, see: Suleiman Gwaram et al. (2011 ▶).

 

Source:

http://doi.org/10.1107/S1600536811022124

 

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