Research Article: Bis(μ-2-{[2-(1,3-benzothia­zol-2-yl)hydrazinyl­idene]meth­yl}-6-meth­oxy­phenolato)bis­[dinitratodysprosium(III)] methanol disolvate

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Xuebin Xu, Shuai Ding, Si Shen, Jinkui Tang, Zhiliang Liu.

http://doi.org/10.1107/S1600536811019118

Abstract

In the centrosymmetric dinuclear title compound, [Dy2(C15H12N3O2S)2(NO3)4]·2CH3OH, the two DyIII atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia­zol-2-yl)hydrazinyl­idene]meth­yl}-6-meth­oxy­phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds and weak O—H⋯O inter­actions, forming a two-dimensional network parallel to (010).

Partial Text

For applications of dysprosium complexes in data storage and processing, see: Lin et al. (2010 ▶). For the preparation of the 2-{[2-(1,3-benzothia­zol-2-yl)hydrazinyl­idene]meth­yl}-6-meth­oxy­phenol ligand, see: Patil et al. (2009 ▶). For related structures, see: Lin & Hong (2009 ▶); Lin et al. (2008 ▶); Xu et al. (2010 ▶).

Source:

http://doi.org/10.1107/S1600536811019118