Research Article: Bis(μ-propan-2-olato-κ2O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]

Date Published: March 01, 2012

Publisher: International Union of Crystallography

Author(s): Nikolai Klishin, Oleksii Brusylovets, Anatoliy Brusilovets, Eduard Rusanov.

http://doi.org/10.1107/S1600536812007799

Abstract

The binuclear centrosymmetric title compound, [Sn2(C3H7O)6Cl2(C3H8O)2], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) Å].

Partial Text

For the synthesis of the title compound, see: Mehrotra & Gupta (1966 ▶). For related structures, see: Chandler et al. (1995 ▶); Genge et al. (1996 ▶); Hampden-Smith et al. (1991 ▶); Reuter & Kremser (1991 ▶, 1993 ▶); Reuter & Schröder (1992 ▶); Sterr & Mattes (1963 ▶); Webster & Collins (1974 ▶); Zhang et al. (2011 ▶). For alcohol adducts of alkoxides, see: Vaartstra et al. (1990 ▶).

 

Source:

http://doi.org/10.1107/S1600536812007799