Research Article: Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) ethane-1,2-diol solvate

Date Published: August 01, 2009

Publisher: International Union of Crystallography

Author(s): Kai-Long Zhong, Chao Ni, Jian-Mei Wang.


In the title compound, [Ni(SO4)(C12H8N2)2]·C2H6O2, the coordination polyhedron around the Ni2+ ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni2+ ion lies on a special position of site symmetry 2. Inter­molecular O—H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

Partial Text

For Ni–phen complexes with chloride anions and water mol­ecules as a second ligand, see: Chen et al. (2005 ▶); Su & Xu (2005 ▶); Tang et al. (2007 ▶). For isostructural compounds, see: Zhong et al. (2006 ▶); Lu et al. (2006 ▶); Zhu et al. (2006a ▶,b ▶).




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