Research Article: Bis[(1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl­propano­ato-κN3]dichlorido­copper(II)

Date Published: May 01, 2012

Publisher: International Union of Crystallography

Author(s): Gang Cao, Ting Guo, Sen Xu.

http://doi.org/10.1107/S1600536812015486

Abstract

In the title compound, [CuCl2(C12H15N3O2)2], the CuII ion is located on an inversion center and is four-coordinated in a distorted square-planar geometry by two chloride anions and two N atoms from two (1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl­propano­ate ligands. The Cl—Cu—N angles of 90.55 (9) and 89.45 (9)° are close to ideal values. In the crystal, weak π–π stacking inter­actions are observed between inversion-related benzene rings [centroid–centroid distance = 4.0028 (6) Å].

Partial Text

For related structures, see: Wang (2008 ▶); Tang et al. (2011 ▶). For the structure of the free benzotriazole ligand, see: Xu & Shen (2012 ▶).

 

Source:

http://doi.org/10.1107/S1600536812015486