Research Article: Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ2N,N′}bis­(thio­cyanato-κN)cadmium

Date Published: February 01, 2012

Publisher: International Union of Crystallography

Author(s): Mohammad Malekshahian, Mohamad Reza Talei Bavil Olyai, Behrouz Notash.

http://doi.org/10.1107/S1600536812002772

Abstract

The title compound, [Cd(NCS)2(C14H14N2)2], features crystallographic inversion symmetry with the CdII ion located on a centre of inversion. The CdII ion is six-coordinated in a slightly distorted octa­hedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An inter­molecular C—H⋯S hydrogen bond stabilizes the crystal structure.

Partial Text

For the medicinal and pharmaceutical application of Schiff base compounds, see: Azza & Abu (2006 ▶); Dudek & Dudek (1966 ▶); Pandeya et al. (1999 ▶); Panneerselvam et al. (2005 ▶); Singh et al. (2006 ▶); Sridhar et al. (2001 ▶); Mladenova et al. (2002 ▶); Walsh et al. (1996 ▶). For the crystal structures of imino­pyridine complexes, see: Talei Bavil Olyai et al. (2008 ▶); Talei Bavil Olyai, Gholami Troujeni et al. (2010 ▶); Talei Bavil Olyai, Razzaghi Fard et al. (2010 ▶); Fallah Nejad et al. (2010 ▶); Loni et al. (2011 ▶).

 

Source:

http://doi.org/10.1107/S1600536812002772