Date Published: July 01, 2012
Publisher: International Union of Crystallography
Author(s): Souheila Ouilia, Chahrazed Beghidja, Adel Beghidja, François Michaud.
In the title complex, [Cu(C9H7N2O2S)2], the CuII ion, located on an inversion center, adopts an N2O2 square-planar coordination. The 2-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)phenolate ligand is chelated to the central CuII ion in an N,O-bidentate manner.
For general background to derivatives of dithiocarbazate ligands and their metal complexes, see: Beghidja et al. (2005 ▶; 2006 ▶); Bouchameni et al. (2011 ▶); Beghidja, Bouslimani & Welter (2007 ▶); Beghidja, Rogez & Welter (2007 ▶). For similar structures, see: Kala et al. (2007 ▶); Liu et al. (2008 ▶); Zhang et al. (2001 ▶). For the preparation of the ligand, see: Dolman et al. (2006 ▶); Young & Wood (1955 ▶).