Date Published: June 01, 2010
Publisher: International Union of Crystallography
Author(s): Tian-Jing He, Yan-Shu Tan, Yun-Qiong Gu, Zhen-Feng Chen, Hong Liang.
The title compound, [Mn(C10H9N4O2S)2(C10H8N2)], contains a distorted octahedral [Mn(sdz)2(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2′-bipyridine) complex molecule. A three-dimensional network is generated by N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds from the sulfadiazine ligands.
For mono-ligand sulfadiazine–metal complexes, see: Yuan et al. (2001 ▶); Wang et al. (2005 ▶). For mixed-ligand sulfadiazine–metal complexes, see: Ajibade et al. (2006 ▶); Brown et al. (1987 ▶); Hossain et al. (2006 ▶); Wang et al. (2009 ▶, 2010 ▶). For 2,2′-bipyridine–Mn(II) complexes, see: Chen et al. (1995 ▶); Cheng et al. (2004 ▶).