Research Article: Bis[4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene-κO2)benzohydrazidato-κ2O,N′]cadmium(II) dimethyl sulfoxide disolvate

Date Published: May 01, 2009

Publisher: International Union of Crystallography

Author(s): Nooraziah Mohd Lair, Hapipah Mohd Ali, Seik Weng Ng.

http://doi.org/10.1107/S1600536809013774

Abstract

The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octa­hedral geometry. Each anion occupies meridional sites of the octa­hedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide mol­ecule is a hydrogen-bond acceptor to the –NH– unit, and O—H⋯O hydrogen bonds link mol­ecules into a supra­molecular chain.

Partial Text

For the monohydrated Schiff base ligand, see: Mohd Lair et al. (2009 ▶).

 

Source:

http://doi.org/10.1107/S1600536809013774

 

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